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    Thermoplastic Composites Taking-off into a Clearer Future

    Composites have had an incredible story from being just 4% in 1970s to having more than 50% share in aircraft structural weight now. Known for its demanding requirements, the aerospace industry has driven significant advancements in material science. In recent years, the spotlight has turned to thermoplastic composites (TPCs). During 2024-2030, the A&D industry is projected to generate a cumulative demand of ~27 million lbs. for thermoplastic composites.

    Published: 11 Sep 2024

    In early 2024, production of the world’s largest thermoplastic composite aircraft fuselage segment was successfully completed by welding two 8-meter-long CFRP (Carbon fiber reinforced plastics) half-shelf. This feat was achieved under the aegis of EU-funded Clean Sky 2/Clean Aviation project ‘Large Passenger Aircraft’ (LPA) by the Fraunhofer- Gesellschaft in Stade, Germany, together with international project partners, which joined together a true-to-scale upper and lower shell of the ‘Multi-Functional Fuselage Demonstrator’ (‘MFFD’) using automated positioning and joining processes.The almost rivet-less structure and the automated pre-integration resulted in 10% savings on each, weight, and cost.Another interesting EU-funded project is the DOMMINIO project (Digital Method for Improved Manufacturing of Next-generation MultIfuNctIOnal airframe parts) which aims to demonstrate technologies enabling multifunctional, intelligent airframe parts that would also have benefits in repair and recycling at the end of life (EOL). The project bets on thermoplastic composites using Toray Advanced Composites TC 1225 unidirectional (UD) tape comprising carbon fiber and LM PAEK polymer by Victrex.There are more such projects where prominent companies in the aerospace and composites industries have joined forces to promote thermoplastic composites and bring them into the mainstream.Known for its demanding requirements, the aerospace industry has driven significant advancements in material science. In recent years, the spotlight has turned to thermoplastic composites (TPCs), a material class that has the potential to revolutionize the way we approach aircraft system design. The Impressive Story of Composites in Aerospace & Defense (A&D)Composites have had an incredible story from being just 4% in 1970s to having more than 50% share in structural weight now. From A300 to A350XWB for Airbus, and from 757/767 to 787 for Boeing, the composites usage has taken a big leap, now accounting for 53% of the material mix of A350XWB and 50% of 787. (Check Figure.1. for composites usage trends in different aircraft programs)The usage of composites in aircraft, however, can be traced back to the World War I & II eras with notable examples like ‘the flying boat’ and ‘the Mistel (mistletoe)’. However, specific details on the type and quantity of composites used in these aircraft are limited.It was also noted that Glass fiber reinforced plastic (GFRP) was the composite structural material used in a wide range of aircraft and missile applications between the 1940s and 1960s. According to the Defense Technical Information Center (DTIC), the A-1E was the first production aircraft to incorporate composite GFRP. Grumman Aircraft produced fiberglass vertical tail structures for this military aircraft. This occurred during the mid-1960s when another breakthrough - ‘Boron fiber reinforcement’ was introduced to the A & D industry.During the 1970s, metals like aluminum, steel, and titanium dominated the aerospace manufacturing industry, comprising ~70% of the average aircraft’s structure. In contrast, the share of composites was infinitesimal, accounting for just 4% of materials used in aircraft manufacturing.The benefits of composites were numerous, and impressive, but there wasn’t any rush in adapting composites in this industry. Gradually, after a lot of research and analyzing the long-term benefits of composites, the industry embarked upon the usage of composite materials.In the early 2000s, the Boeing 787 Dreamliner broke new ground as the world’s first major commercial airliner to feature a primary airframe constructed from composite material. The aircraft is notable for its extensive use of composite materials, comprising ~80% of its volume and 50% (that is approximately 32,000 kgs of carbon fiber reinforced composite) of its total weight. Each Boeing 787 aircraft then used composites for wings, tails, doors, fuselage, and interior.Not just Boeing, but other aviation giants like Bombardier, BAE systems, Raytheon, Lockheed Martin, and GE Aviation gradually jumped on the bandwagon of using composites in their aircraft. Figure1: Composites Usage Penetration Trend in Different Aircraft Programs  Evolution of Thermoplastic CompositesThroughout this transition, thermoset composites and autoclave processing have been the predominant choices for manufacturing aircraft components. Since the outset of this century, out of autoclave (OOA) processing techniques have begun attracting interest owing to the possibilities of faster production and lower fabrication costs, which is the industry’s priority. Owing to their properties, the surge in interest in OOA paved the way for the adoption of new materials - thermoplastic composites - which are well-suited to these processing methods.Applications of thermoplastic composites date back to the US military’s F-22 jet fighter’s landing-gear and weapons-bay doors in the 1980s, and the outer wing trailing edge skin panel or shroud for the Fokker 50 passenger aircraft in the 1990s. (Check the evolution of TPCs in Figure.2.)Figure 2: Evolution of TPCsToday, most of the modern aircraft feature thermoplastic composites in several applications, such as clips, cleats, fixed-wing leading edges, J-nose leading edges, panels for fuselage, profiles & brackets, ribs & angle brackets, control surface parts, seat backs, window panels, and cockpit floor.Clips and cleats are considered to be the largest applications of thermoplastic composites in the industry and are made from carbon fibers with either PPS or PEEK resins. There are about 8,000 clips and cleats used in each A350XWB and about 10,000-15,000 clips and cleats in a B787 aircraft.  Figure 3: Key Applications of Thermoplastic Composites in an Aircraft  Thermoplastics Vs ThermosetsCurrently, thermoset composites dominate the A&D composites market; however, thermoplastic composites are successful in marking their presence in the structural sections of an aircraft by replacing both thermoset composites as well as traditional metals.Unlike their thermoset counterparts, thermoplastics are capable of being reheated and reshaped repeatedly without losing their structural integrity. Known as thermoplasticity, this unique property enhances thermoplastic composites’ recyclability.Here’s a quick rundown of the differences between ‘thermosets’ and ‘thermoplastics’ - Properties Thermosets Thermoplastics Viscosity Low High Chemical Resistance High Moderate Toughness Moderate High Age (Shelf life) Moderate Infinite Reusability (Thermoformable) Low High Cost Medium High Melting Point High Low Molecular Weight High Low Overall Cost Savings Low High Table 1: Property Comparison of Thermosets & Thermoplastics Owing to their many benefits, thermoplastic composite materials in the A&D industry are witnessing an illustrious journey. Valued at US$ 330 million in 2023, the global aerospace thermoplastic composites industry is expected to reach US$ 870 million in 2030, growing at a skyrocketing annual growth of >14%.It is important to note that the above figure represents only a fraction of the overall composite usage in the A&D industry. Despite the impressive growth, thermoplastic composites (TPCs) still account for merely 2% of total composites usage in the A&D industry which is around 34.5 million pounds.Once considered unsafe for even structural components, TPCs are now being applied to critical control surfaces too. Figure 4: Thermoplastic Composites Contribution in the A&D Composites Market in 2023 (Volume) 

    The Long Run of Composites in Orthopaedics

    The use of composite materials in orthopaedics is rapidly increasing, with the market estimated to reach USD 286 million in 2024 and grow at a CAGR of over 5% to cross USD 385 million by 2030.

    Published: 12 Aug 2024

    Remember the man at the centre of the cover image? He is Oscar Pistorius, also known as the ‘Blade Runner’, and the first double-leg amputee to compete in summer Olympic Games in 2012.The artificial legs (blades) which made it possible and rendered him speed were made of carbon fibre-reinforced polymer (CFRP). 12 years are passed, and carbon fibre-reinforced polymer (CFRP) prosthetics are now a common-place at various international sporting events.Composites are gaining popularity in modern-day orthopaedics and are used in orthotic and prosthetic manufacturing. According to Stratview Research, the market for orthopaedic composites will reach USD 286 million in 2024. (See Figure 1) Fig. 1: Global Orthopaedic Composites Market Forecast (2025-2030)The human bones are themselves composites and are made of both hard and soft materials: calcium and collagen. According to the National Institutes of Health (NIH), bone is the second most frequently transplanted tissue after blood, with over two million transplants performed worldwide every year. Orthopaedic surgeries can trigger immune systems, making it essential for any implant material to function as effectively as natural tissue.Traditional materials like nickel, chromium, cobalt, and ceramics pose risks of infection since they rapidly degrade in the body’s atmosphere. In fact, the most frequently- used material for orthopaedic implants - Titanium is also prone to hypersensitivity, and in some cases, titanium alloy hypersensitivity has also resulted in failed hip prostheses, cardiac pacemaker implantation, and more. Such failures often necessitate revision surgeries.To address the challenges posed by metals, their composite counterparts having superior strength and biocompatibility properties, that are capable of safely and gradually degrading in the body within the required healing time, are being used in the orthopaedic industry. The introduction of composite materials in the orthopaedic industry created a buzz addressing various challenges. Let us explore more.

    Composite Textiles and the Many Layers of Opportunities

    Although the applications of composite textiles are multi-directional, there are several factors that may slow down the growth pace. High cost of raw materials and the requirement for skilled manpower are among the biggest roadblocks for this industry.

    Published: 10 Oct 2023

    When we hear the word ‘textile’, the first few words that usually pop into our minds are fabrics, suits, texture, or maybe even our favorite clothing brand. But, the advancement of technology has broadened both the scope and the applications of textiles so much that starting from the circuit board in your mobile phone, to complex parts of an aircraft, everything today is being made using textiles. However, not every textile is capable of offering the flexibility of being used in such a wide range of applications, and hence composite textiles have been the ‘go-to’ material across several industries for quite some time now. Every Industry that Requires Lightweighting, Requires Composites: Known for their exceptional structural properties combined with their lightweighting capabilities, composite textiles find applications in every industry where durability and lightweighting are the key design requirements. This includes the entire mobility sector because of their common aim of achieving reduced emissions and better fuel efficiency, the wind energy sector, construction, electronics, and many other industries. Listed below are some key applications of composite textiles across these industries. Fig. 1: Key applications of composite textiles The industries combinedly have the potential to generate a demand of ~$7.2 bn worth of composite textiles in 2023, which would scale up to $9.5 bn by 2028, according to Stratview Research. Although the focus on increasing the penetration of composites is more in the automotive, aerospace, and marine industries; the biggest share of the demand for composite textiles is generated by the Wind Energy sector, followed by the Electrical and Electronics sector, currently and in the coming years as well. Close to 50% of the current demand for composite textiles in the market is generated by these two industries alone according to an analysis from Stratview Research. Fig. 2: Composite textiles market trend and forecast (US$ billion)

    FCEVs Driving the Carbon Composite Hydrogen Tanks

    It is expected that by 2030, FCEVs will account for >1% of the global powertrain mix, which would represent around 1.2 to 1.7 million hydrogen vehicles including lightweight and commercial vehicles, each one of which will be equipped with CCHTs for hydrogen storage.

    Published: 03 Aug 2023

    In 2014, Toyota opened the doors to the hydrogen society by launching Toyota Mirai, the world’s first commercial FCEV (Fuel Cell Electric Vehicle). However, Mirai was not the first FCEV developed in the world. The credit of introducing the first FCEV to the world goes to General Motors, which developed Electrovan more than a half century ago in 1966. The GM Electrovan containing 2 giant storage tanks for hydrogen and oxygen, 32 fuel cell modules, electric motor, and a 550-feet piping throughout the rear of the vehicle weighted around 7,100 pounds. This system relied on rare metals including platinum, which made it too expensive, and no proper hydrogen infrastructure was there those days, which made this vehicle a failure. From GM Electrovan, that had a range of just 160 Kms, to today’s fuel cell vehicles that can range easily more than 600 Kms, the new-age fuel cell vehicles have seen a transition of innovation. An era of risky storage, prohibitive cost, and with less room has ended with the dawn of high-pressure vessels, specifically – Carbon Composite Hydrogen Tanks (CCHTs) for fuel storage. Carbon Composite Hydrogen Tanks, Their Types, & Applications CCHTs are the pressure vessels fully wrapped by carbon composites with metallic or polymeric liners (Type III & Type IV). Type III tank has a metal liner (aluminium or steel) with full composite overwrap, whereas Type IV is a complete carbon fiber made tank having an inner liner made of polyamide or polyethylene plastic. In 2021, hydrogen pressure vessels had nearly 7% share of the total pressure vessels market, a majority of which is CCHT. Table.1. Types of Pressure Vessels The reason behind preferring carbon composites for the new-age hydrogen pressure vessels is that these materials are known for their superior strength & durability along with light weight, offering a mass-reduction between 50%-70%. CCHTs find usage in a variety of applications, including cars, buses, trucks, forklifts, trains, ships, refuelling stations, bulk gas transportation, and back-up power. However, FCEV is the one application which generates over 90% of the demand for CCHTs.

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    Tags:

    Polyetheretherketone (PEEK) | Composites in Aerospace and Defence | PEEK | Thermoplastic Composites | Carbon Fiber Reinforced Plastics | Prosthetics | Orthopaedic Composites | Marine Composites | Membrane | Waterproofing |

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